Keep in mind the war hasnt knocked us back to the 1850's - more like to the 1910-20 level -and as was shown mankind was damn proficient back then at chemical warfare - the rounds won't be binary rounds - they will probably be simple ones similar to 1915-18 ones but still deadly - especially against civilians and troops whose NBC gear is no longer functional and who dont have access to records of how troops dealt with those kinds of weapons in WWI
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